(Ferrocenylmethyl)trimethylammonium perchlorate
نویسنده
چکیده
The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(9)H(15)N)]ClO(4), contains one discrete (ferrocenylmeth-yl)trimethyl-ammonium cation and one perchlorate anion. The anion is disordered over two sets of sites, with refined occupancies of 0.776 (8) and 0.224 (8). The distances from the Fe atom to the centroids of the unsubstituted and substituted cyclo-penta-dienyl (Cp) rings are 1.650 (1) and 1.640 (1) Å, respectively. The Cp rings form a dihedral angle of 2.66 (3)°.
منابع مشابه
Allyl(ferrocenylmethyl)dimethylammonium perchlorate
The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(11)H(17)N)]ClO(4), contains two independent all-yl(ferro-cenyl-meth-yl)dimethyl-ammonium cations and two ClO(4) (-) anions. The anions are disordered each over two sets of sites, with an occupancy ratio of 0.617 (6):0.383 (6). The distances from the Fe atoms to the centroids of the unsubstituted and substituted cyclo-penta-dienyl (Cp) ri...
متن کامل(Ferrocenylmethyl)dimethylammonium bromide
The title compound, [Fe(C(5)H(5))(C(8)H(13)N)]Br, is isotypic with the analogous chloride compound. The Fe-C bond lengths are in the range 2.020 (6)-2.048 (7) Å. In the crystal, the cations and bromide anions are connected by N(+)-H⋯Br(-) hydrogen bonds.
متن کامل1-Ferrocenylmethyl-1H-imidazole
In the title compound, [Fe(C(5)H(5))(C(9)H(9)N(2))], the distances of the Fe atom from the centroids of the unsubstituted and the substituted cyclo-penta-dienyl (cp) rings are 1.639 (1) and 1.647 (1) Å, respectively. The ferrocenyl unit deviates from an eclipsed geometry with tilted cp rings; the inter-planar angle between the cp and imidazole rings is 114.11 (4)°.
متن کاملEnvironmental factors that control microbial perchlorate reduction.
As part of a study to elucidate the environmental parameters that control microbial perchlorate respiration, we investigated the reduction of perchlorate by the dissimilatory perchlorate reducer Dechlorosoma suillum under a diverse set of environmental conditions. Our results demonstrated that perchlorate reduction by D. suillum only occurred under anaerobic conditions in the presence of perchl...
متن کامل- 15 - 1 - CHAPTER 15 . Biodegradation of Perchlorate
Perchlorate (ClO4) has been detected in some states in the U.S and become an environmental concern since the late 1990’s. Perchlorate properties, contamination, and health effects were introduced in this paper. Perchlorate biodegradation degradation were introduced and summarized. According to recent studies, perchlorate respiring bacteria are present in natural environments, providing possibil...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012